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What is Entropy?

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University Course Reader · STEM

Because the process is irreversible, the total entropy of the isolated system must increase in accordance with the second law.

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Entropy is a state function quantifying the number of microstates consistent with a system's macrostate, formalized as S = k ln W. Per the second law of thermodynamics, the entropy of an isolated system is non-decreasing, rendering spontaneous processes irreversible in the thermodynamic limit. Local entropy reductions require compensating increases in the surroundings.

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